Semiconductors & p–n Junctions — A/L Physics
Aligned with the NIE syllabus
What must I remember about Semiconductors & p–n Junctions?
- Intrinsic Semiconductors: Pure tetravalent crystals (Silicon, Germanium) where electrical conduction at room temperature occurs via equal concentrations of thermally generated electron-hole pairs (ni = pi).
- Extrinsic Semiconductors & Doping: Doping with pentavalent atoms (P, As, Sb) adds free donor electrons creating n-type semiconductor (majority carriers: electrons; minority carriers: holes); Doping with trivalent atoms (B, Al, Ga, In) creates acceptor holes yielding p-type semiconductor (majority carriers: holes; minority carriers: electrons).
- p-n Junction Formation & Depletion Layer: Majority carriers diffuse across junction (electrons to p-side, holes to n-side), leaving behind uncompensated immobile donor ions (positive) in n-region and acceptor ions (negative) in p-region, establishing a Depletion Region devoid of mobile charge carriers.
- Barrier Potential (Built-in Potential V0): The internal electrostatic field in depletion region opposes further majority carrier diffusion; Barrier potential V0 ≈ 0.7 V for Silicon and ≈ 0.3 V for Germanium at room temperature.
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Biasing Effects on Depletion Layer
Forward Bias (p connected to +, n connected to -): External field opposes internal barrier field, narrowing depletion layer, reducing barrier height, permitting heavy exponential majority carrier forward current; Reverse Bias (p connected to -, n connected to +): External field reinforces barrier field, widening depletion layer, blocking majority flow.
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Reverse Saturation Current (Is)
In reverse bias, a minute leakage current (~nanoamperes in Si, microamperes in Ge) flows due to thermally generated minority carriers swept across junction; strongly temperature dependent.
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Electrical Neutrality of Doped Semiconductors
Despite being called n-type and p-type, the bulk materials remain electrically NEUTRAL overall because donor and acceptor atoms were originally neutral.
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Source: NIE G.C.E. (A/L) Physics Resource Book - Unit 9: Electronics
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Where does Semiconductors & p–n Junctions fit in the syllabus?
Unit 9.1 · Year 2 · Term 2
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